Cocrystallization of poly(1,4-cyclohexylenedimethylene terephthalate-co-hexamethylene terephthalate) copolymers
نویسندگان
چکیده
منابع مشابه
Synthesis, Characterization, and Ring Opening Polymerization of Poly(1,4-cyclohexylenedimethylene terephthalate) Cyclic Oligomers
Cyclic oligomers of poly(1,4-cyclohexylenedimethylene terephthalate) (PCT) were prepared by reaction of 1,4-cyclohexanedimethanol (CHDM) with terephthaloyl chloride under diluted conditions and separated from the linear products by silica gel column at a yield of 23.7 wt %. Cyclic dimer, trimer, tetramer, pentamer, and hexamer were further separated by high performance liquid chromatography, an...
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The asymmetric unit of the title salt, 2C(2)H(8)NO(+)·C(8)H(4)O(4) (2-), comprises one crystallographically independent 2-hy-droxy-ethanaminium cation and one half terephthalate anion. In the crystal, hydrogen bonds involving the hy-droxy and ammonium groups of the cations and the carboxyl-ate O atoms of the terephthalate anions result in the formation of a three-dimensional network structure.
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The asymmetric unit of the title salt, C(4)H(12)N(+)·C(8)H(5)O(4) (-), contains one half of a tetra-methyl-ammonium cation and one half of a hydrogen terephthalate monoanion. The N atom of the ammonium cation lies on a twofold rotation axis and the centre of mass of the terephthalate anion is on a centre of inversion. In the crystal, the centrosymmetric terephthalate ions are linked by a very s...
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The asymmetric unit of the title compound, C(5)H(9)N(2) (+)·C(8)H(5)O(4) (-), consists of one protonated 2-ethyl-imidazolium cation and two half terephthalate anions. The anions and cations are linked through N-H⋯O hydrogen bonds while the anions are associated via O-H⋯O inter-actions, resulting in a layered structure. The ethyl group of the cation is disordered over twosites of occupancies 0.8...
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Poly (butylene adipate-co-terephthalate) PBAT is a synthetic biodegradable polymer commonly used for plastic film production from neat polymer or nanocomposites. The PBAT is submitted to high temperatures and shear rate during its processing. In the present study, the thermo stabilisation of PBAT by the addition of two types of stabilisers was studied using a torque rheometer at 60 rpm and two ...
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ژورنال
عنوان ژورنال: Macromolecular Research
سال: 2004
ISSN: 1598-5032,2092-7673
DOI: 10.1007/bf03218427